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Lead And Zinc Ores, major discharger, Fredericktown, Missouri. NPDES permit MO0098752, in force until Jun 30, 2029. Last 12 months: over a limit 93 times (last August 2026). Source: EPA ECHO, Oct 22, 2026.
| Period ending | Outfall | Parameter | Reported | Limit | Over by |
|---|---|---|---|---|---|
| October 2025 | 001 | Chlorides + Sulfates, daily maximum | 1055.74 | ≤ 1000 mg/L | 6% |
| October 2025 | 001 | Chlorides + Sulfates, monthly average | 1055.74 | ≤ 1000 mg/L | 6% |
| October 2025 | 002 | Cadmium, total recoverable, monthly average | .3 | ≤ .2 ug/L | 50% |
| October 2025 | 002 | Cobalt, total recoverable, monthly average | 1010 | ≤ 693 ug/L | 46% |
| October 2025 | 002 | Copper, total recoverable, daily maximum | 25.7 | ≤ 15.3 ug/L | 68% |
| October 2025 | 002 | Copper, total recoverable, monthly average | 25.7 | ≤ 5.6 ug/L | 359% |
| October 2025 | 002 | Nickel, total recoverable, daily maximum | 1590 | ≤ 80.9 ug/L | 1865% |
| October 2025 | 002 | Nickel, total recoverable, monthly average | 1590 | ≤ 49.9 ug/L | 3086% |
| November 2025 | 002 | Cadmium, total recoverable, monthly average | .3 | ≤ .2 ug/L | 50% |
| November 2025 | 002 | Cobalt, total recoverable, monthly average | 1050 | ≤ 693 ug/L | 52% |
| November 2025 | 002 | Copper, total recoverable, daily maximum | 28.4 | ≤ 15.3 ug/L | 86% |
| November 2025 | 002 | Copper, total recoverable, monthly average | 28.4 | ≤ 5.6 ug/L | 407% |
| November 2025 | 002 | Lead, total recoverable, monthly average | 6.1 | ≤ 2.2 ug/L | 177% |
| November 2025 | 002 | Nickel, total recoverable, daily maximum | 1620 | ≤ 80.9 ug/L | 1902% |
| November 2025 | 002 | Nickel, total recoverable, monthly average | 1620 | ≤ 49.9 ug/L | 3146% |
| December 2025 | 002 | Cobalt, total recoverable, monthly average | 1000 | ≤ 693 ug/L | 44% |
| December 2025 | 002 | Copper, total recoverable, daily maximum | 28.6 | ≤ 15.3 ug/L | 87% |
| December 2025 | 002 | Copper, total recoverable, monthly average | 28.6 | ≤ 5.6 ug/L | 411% |
| December 2025 | 002 | Nickel, total recoverable, daily maximum | 1630 | ≤ 80.9 ug/L | 1915% |
| December 2025 | 002 | Nickel, total recoverable, monthly average | 1630 | ≤ 49.9 ug/L | 3167% |
| December 2025 | 002 | Toxicity [acute], Ceriodaphnia dubia, value | > 16 | ≤ .3 toxic | — |
| January 2026 | 001 | Chlorides + Sulfates, daily maximum | 1085.1 | ≤ 1000 mg/L | 9% |
| January 2026 | 001 | Chlorides + Sulfates, monthly average | 1085.1 | ≤ 1000 mg/L | 9% |
| January 2026 | 002 | Cobalt, total recoverable, monthly average | 1060 | ≤ 693 ug/L | 53% |
| January 2026 | 002 | Copper, total recoverable, daily maximum | 51.9 | ≤ 15.3 ug/L | 239% |
| January 2026 | 002 | Copper, total recoverable, monthly average | 51.9 | ≤ 5.6 ug/L | 827% |
| January 2026 | 002 | Lead, total recoverable, monthly average | 6.4 | ≤ 2.2 ug/L | 191% |
| January 2026 | 002 | Nickel, total recoverable, daily maximum | 1720 | ≤ 80.9 ug/L | 2026% |
| January 2026 | 002 | Nickel, total recoverable, monthly average | 1720 | ≤ 49.9 ug/L | 3347% |
| February 2026 | 001 | Lead, total recoverable, daily maximum | 7.2 | ≤ 6.5 ug/L | 11% |
| February 2026 | 001 | Lead, total recoverable, monthly average | 7.2 | ≤ 2.2 ug/L | 227% |
| February 2026 | 002 | Cobalt, total recoverable, monthly average | 700 | ≤ 693 ug/L | 1% |
| February 2026 | 002 | Copper, total recoverable, daily maximum | 20.6 | ≤ 15.3 ug/L | 35% |
| February 2026 | 002 | Copper, total recoverable, monthly average | 20.6 | ≤ 5.6 ug/L | 268% |
| February 2026 | 002 | Nickel, total recoverable, daily maximum | 1130 | ≤ 80.9 ug/L | 1297% |
| February 2026 | 002 | Nickel, total recoverable, monthly average | 1130 | ≤ 49.9 ug/L | 2165% |
| March 2026 | 001 | Lead, total recoverable, daily maximum | 33.2 | ≤ 6.5 ug/L | 411% |
| March 2026 | 001 | Lead, total recoverable, monthly average | 20.1 | ≤ 2.2 ug/L | 814% |
| March 2026 | 001 | Solids, total suspended, daily maximum | 79 | ≤ 45 mg/L | 76% |
| March 2026 | 001 | Solids, total suspended, monthly average | 42.5 | ≤ 30 mg/L | 42% |
| March 2026 | 002 | Cadmium, total recoverable, daily maximum | .8 | ≤ .5 ug/L | 60% |
| March 2026 | 002 | Cadmium, total recoverable, monthly average | .8 | ≤ .2 ug/L | 300% |
| March 2026 | 002 | Copper, total recoverable, daily maximum | 152 | ≤ 15.3 ug/L | 893% |
| March 2026 | 002 | Copper, total recoverable, monthly average | 152 | ≤ 5.6 ug/L | 2614% |
| March 2026 | 002 | Lead, total recoverable, daily maximum | 137 | ≤ 6.5 ug/L | 2008% |
| March 2026 | 002 | Lead, total recoverable, monthly average | 137 | ≤ 2.2 ug/L | 6127% |
| March 2026 | 002 | Nickel, total recoverable, daily maximum | 130 | ≤ 80.9 ug/L | 61% |
| March 2026 | 002 | Nickel, total recoverable, monthly average | 130 | ≤ 49.9 ug/L | 161% |
| March 2026 | 002 | Solids, total suspended, daily maximum | 187 | ≤ 45 mg/L | 316% |
| March 2026 | 002 | Solids, total suspended, monthly average | 187 | ≤ 30 mg/L | 523% |
| March 2026 | 002 | Toxicity [acute], Ceriodaphnia dubia, value | > 16 | ≤ .3 toxic | — |
| March 2026 | 002 | Zinc, total recoverable, daily maximum | 174 | ≤ 130.2 ug/L | 34% |
| March 2026 | 002 | Zinc, total recoverable, monthly average | 174 | ≤ 87 ug/L | 100% |
| April 2026 | 001 | Cadmium, total recoverable, monthly average | < .3 | ≤ .2 ug/L | 50% |
| April 2026 | 001 | Lead, total recoverable, monthly average | 2.3 | ≤ 2.2 ug/L | 5% |
| April 2026 | 002 | Cadmium, total recoverable, monthly average | < .3 | ≤ .2 ug/L | 50% |
| April 2026 | 002 | Cobalt, total recoverable, daily maximum | 1190 | ≤ 1103 ug/L | 8% |
| April 2026 | 002 | Cobalt, total recoverable, monthly average | 1190 | ≤ 693 ug/L | 72% |
| April 2026 | 002 | Copper, total recoverable, daily maximum | 24.9 | ≤ 15.3 ug/L | 63% |
| April 2026 | 002 | Copper, total recoverable, monthly average | 24.9 | ≤ 5.6 ug/L | 345% |
| April 2026 | 002 | Lead, total recoverable, monthly average | 2.9 | ≤ 2.2 ug/L | 32% |
| April 2026 | 002 | Nickel, total recoverable, daily maximum | 1820 | ≤ 80.9 ug/L | 2150% |
| April 2026 | 002 | Nickel, total recoverable, monthly average | 1820 | ≤ 49.9 ug/L | 3547% |
| May 2026 | 001 | Chlorides + Sulfates, daily maximum | 1040 | ≤ 1000 mg/L | 4% |
| May 2026 | 001 | Chlorides + Sulfates, monthly average | 1040 | ≤ 1000 mg/L | 4% |
| May 2026 | 002 | Cadmium, total recoverable, daily maximum | .6 | ≤ .5 ug/L | 20% |
| May 2026 | 002 | Cadmium, total recoverable, monthly average | .6 | ≤ .2 ug/L | 200% |
| May 2026 | 002 | Cobalt, total recoverable, daily maximum | 1240 | ≤ 1103 ug/L | 12% |
| May 2026 | 002 | Cobalt, total recoverable, monthly average | 1240 | ≤ 693 ug/L | 79% |
| May 2026 | 002 | Copper, total recoverable, daily maximum | 15.5 | ≤ 15.3 ug/L | 1% |
| May 2026 | 002 | Copper, total recoverable, monthly average | 15.5 | ≤ 5.6 ug/L | 177% |
| May 2026 | 002 | Nickel, total recoverable, daily maximum | 1780 | ≤ 80.9 ug/L | 2100% |
| May 2026 | 002 | Nickel, total recoverable, monthly average | 1780 | ≤ 49.9 ug/L | 3467% |
| June 2026 | 001 | Chlorides + Sulfates, daily maximum | 1030 | ≤ 1000 mg/L | 3% |
| June 2026 | 001 | Chlorides + Sulfates, monthly average | 1030 | ≤ 1000 mg/L | 3% |
| June 2026 | 001 | Lead, total recoverable, monthly average | 3.2 | ≤ 2.2 ug/L | 45% |
| June 2026 | 001 | Solids, total suspended, daily maximum | 59 | ≤ 45 mg/L | 31% |
| June 2026 | 001 | Solids, total suspended, monthly average | 59 | ≤ 30 mg/L | 97% |
| June 2026 | 002 | Cadmium, total recoverable, monthly average | .3 | ≤ .2 ug/L | 50% |
| June 2026 | 002 | Cobalt, total recoverable, monthly average | 815 | ≤ 693 ug/L | 18% |
| June 2026 | 002 | Copper, total recoverable, monthly average | 9.6 | ≤ 5.6 ug/L | 71% |
| June 2026 | 002 | Nickel, total recoverable, daily maximum | 1310 | ≤ 80.9 ug/L | 1519% |
| June 2026 | 002 | Nickel, total recoverable, monthly average | 1310 | ≤ 49.9 ug/L | 2525% |
| June 2026 | 002 | Solids, total suspended, daily maximum | 46 | ≤ 45 mg/L | 2% |
| June 2026 | 002 | Solids, total suspended, monthly average | 46 | ≤ 30 mg/L | 53% |
| June 2026 | 002 | Toxicity [acute], Ceriodaphnia dubia, value | > 16 | ≤ .3 toxic | — |
| August 2026 | 001 | Lead, total recoverable, monthly average | 3.5 | ≤ 2.2 ug/L | 59% |
| August 2026 | 002 | Cadmium, total recoverable, monthly average | .4 | ≤ .2 ug/L | 100% |
| August 2026 | 002 | Copper, total recoverable, monthly average | 7.4 | ≤ 5.6 ug/L | 32% |
| August 2026 | 002 | Lead, total recoverable, daily maximum | 38.5 | ≤ 6.5 ug/L | 492% |
| August 2026 | 002 | Lead, total recoverable, monthly average | 38.5 | ≤ 2.2 ug/L | 1650% |
| August 2026 | 002 | Solids, total suspended, daily maximum | 208 | ≤ 45 mg/L | 362% |
| August 2026 | 002 | Solids, total suspended, monthly average | 208 | ≤ 30 mg/L | 593% |
| Parameter | Statistic | Limit | Months | Outfall |
|---|---|---|---|---|
| Sulfate [as S] | daily maximum | report only (mg/L) | all year | 001 |
| Sulfate [as S] | monthly average | report only (mg/L) | all year | 001 |
| pH | minimum | ≥ 6.5 SU | all year | 001 |
| pH | maximum | ≤ 9 SU | all year | 001 |
| Solids, total suspended | daily maximum | ≤ 45 mg/L | all year | 001 |
| Solids, total suspended | monthly average | ≤ 30 mg/L | all year | 001 |
| Oil and grease [soxhlet extr.] tot. | daily maximum | report only (mg/L) | all year | 001 |
| Oil and grease [soxhlet extr.] tot. | monthly average | report only (mg/L) | all year | 001 |
| Cyanide, total [as CN] | daily maximum | report only (ug/L) | all year | 001 |
| Cyanide, total [as CN] | monthly average | report only (ug/L) | all year | 001 |
| Arsenic, total recoverable | daily maximum | report only (ug/L) | all year | 001 |
| Arsenic, total recoverable | monthly average | report only (ug/L) | all year | 001 |
| Cobalt, total recoverable | daily maximum | ≤ 1103 ug/L | all year | 001 |
| Cobalt, total recoverable | monthly average | ≤ 693 ug/L | all year | 001 |
| Nickel, total recoverable | daily maximum | ≤ 80.9 ug/L | all year | 001 |
| Nickel, total recoverable | monthly average | ≤ 49.9 ug/L | all year | 001 |
| Zinc, total recoverable | daily maximum | ≤ 130.2 ug/L | all year | 001 |
| Zinc, total recoverable | monthly average | ≤ 87 ug/L | all year | 001 |
| Cadmium, total recoverable | daily maximum | ≤ .5 ug/L | all year | 001 |
| Cadmium, total recoverable | monthly average | ≤ .2 ug/L | all year | 001 |
| Lead, total recoverable | daily maximum | ≤ 6.5 ug/L | all year | 001 |
| Lead, total recoverable | monthly average | ≤ 2.2 ug/L | all year | 001 |
| Chloride | daily maximum | report only (mg/L) | all year | 001 |
| Chloride | monthly average | report only (mg/L) | all year | 001 |
| Flow, in conduit or thru treatment plant | daily maximum | report only (MGD) | all year | 001 |
| Flow, in conduit or thru treatment plant | monthly average | report only (MGD) | all year | 001 |
| Toxicity [acute], Ceriodaphnia dubia | value | ≤ .3 toxic | all year | 001 |
| Toxicity [acute], Pimephales promelas [Fathead Minnow] | value | ≤ .3 toxic | all year | 001 |
| Chlorides + Sulfates | daily maximum | ≤ 1000 mg/L | all year | 001 |
| Chlorides + Sulfates | monthly average | ≤ 1000 mg/L | all year | 001 |
| Sulfate [as S] | daily maximum | report only (mg/L) | all year | 002 |
| Sulfate [as S] | monthly average | report only (mg/L) | all year | 002 |
| pH | minimum | ≥ 6.5 SU | all year | 002 |
| pH | maximum | ≤ 9 SU | all year | 002 |
| Solids, total suspended | daily maximum | ≤ 45 mg/L | all year | 002 |
| Solids, total suspended | monthly average | ≤ 30 mg/L | all year | 002 |
| Oil and grease [soxhlet extr.] tot. | daily maximum | report only (mg/L) | all year | 002 |
| Oil and grease [soxhlet extr.] tot. | monthly average | report only (mg/L) | all year | 002 |
| Cyanide, total [as CN] | daily maximum | report only (ug/L) | all year | 002 |
| Cyanide, total [as CN] | monthly average | report only (ug/L) | all year | 002 |
| Cobalt, total recoverable | daily maximum | ≤ 1103 ug/L | all year | 002 |
| Cobalt, total recoverable | monthly average | ≤ 693 ug/L | all year | 002 |
| Arsenic, total [as As] | daily maximum | report only (ug/L) | all year | 002 |
| Arsenic, total [as As] | monthly average | report only (ug/L) | all year | 002 |
| Nickel, total recoverable | daily maximum | ≤ 80.9 ug/L | all year | 002 |
| Nickel, total recoverable | monthly average | ≤ 49.9 ug/L | all year | 002 |
| Zinc, total recoverable | daily maximum | ≤ 130.2 ug/L | all year | 002 |
| Zinc, total recoverable | monthly average | ≤ 87 ug/L | all year | 002 |
| Cadmium, total recoverable | daily maximum | ≤ .5 ug/L | all year | 002 |
| Cadmium, total recoverable | monthly average | ≤ .2 ug/L | all year | 002 |
| Lead, total recoverable | daily maximum | ≤ 6.5 ug/L | all year | 002 |
| Lead, total recoverable | monthly average | ≤ 2.2 ug/L | all year | 002 |
| Copper, total recoverable | daily maximum | ≤ 15.3 ug/L | all year | 002 |
| Copper, total recoverable | monthly average | ≤ 5.6 ug/L | all year | 002 |
| Chloride | daily maximum | report only (mg/L) | all year | 002 |
| Chloride | monthly average | report only (mg/L) | all year | 002 |
| Flow, in conduit or thru treatment plant | daily maximum | report only (MGD) | all year | 002 |
| Flow, in conduit or thru treatment plant | monthly average | report only (MGD) | all year | 002 |
| Toxicity [acute], Ceriodaphnia dubia | value | ≤ .3 toxic | all year | 002 |
| Toxicity [acute], Pimephales promelas [Fathead Minnow] | value | ≤ .3 toxic | all year | 002 |
| Chlorides + Sulfates | daily maximum | ≤ 1000 mg/L | all year | 002 |
| Chlorides + Sulfates | monthly average | ≤ 1000 mg/L | all year | 002 |
| Freeboard | daily minimum | ≥ 2 ft | all year | 006 |
| Freeboard | monthly average | report only (ft) | all year | 006 |
| Oxygen demand, chem. [high level] [COD] | daily maximum | report only (mg/L) | all year | 008 |
| pH | minimum | report only (SU) | all year | 008 |
| pH | maximum | report only (SU) | all year | 008 |
| Solids, total suspended | daily maximum | report only (mg/L) | all year | 008 |
| Oil and grease [soxhlet extr.] tot. | daily maximum | report only (mg/L) | all year | 008 |
| Cyanide, total [as CN] | daily maximum | report only (ug/L) | all year | 008 |
| Arsenic, total recoverable | daily maximum | report only (ug/L) | all year | 008 |
| Cobalt, total recoverable | daily maximum | report only (ug/L) | all year | 008 |
| Nickel, total recoverable | daily maximum | report only (ug/L) | all year | 008 |
| Zinc, total recoverable | daily maximum | report only (ug/L) | all year | 008 |
| Cadmium, total recoverable | daily maximum | report only (ug/L) | all year | 008 |
| Lead, total recoverable | daily maximum | report only (ug/L) | all year | 008 |
| Copper, total recoverable | daily maximum | report only (ug/L) | all year | 008 |
| Storm water flow | daily maximum | report only (MGD) | all year | 008 |
| Freeboard | daily minimum | ≥ 2 ft | all year | 009 |
| Freeboard | monthly average | report only (ft) | all year | 009 |
| Sulfate [as S] | daily maximum | report only (mg/L) | all year | MDW |
| Sulfate [as S] | monthly average | report only (mg/L) | all year | MDW |
| Chlorides + Sulfates | daily maximum | report only (mg/L) | all year | MDW |
| Chlorides + Sulfates | monthly average | report only (mg/L) | all year | MDW |
| Parameter | New limit | New or tighter | Median, last 12 months | × new limit |
|---|---|---|---|---|
| Cyanide, total [as CN], daily maximum | 8.5 ug/L | new | — | — |
| Cyanide, total [as CN], monthly average | 4.3 ug/L | new | — | — |
Cited limits by parameter: Missouri's rules and the federal ones.
Same industry: the 12 Metal Mining permits in Missouri.
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