{"query":{"parameter":"4 4 methylenedi phenyl isocyanate","place":"US-FL","medium":null,"statistic":null,"kind":null},"searched":{"places":["US-FL","US"],"parameter_keys":["cas:101-68-8","cas:9016-87-9"],"names_matched":[["4 4 methylenedi phenyl isocyanate","cas:101-68-8"],["polymeric methylene diphenyl diisocyanate pmdi","cas:9016-87-9","methylene diphenyl diisocyanate"]],"match":"exact+contains","order":"The place's own instruments first, then each place above it, each in its register's order","not_sent":{"rows":2,"names":["Polymeric Methylene Diphenyl Diisocyanate (PMDI)"],"says":"2 rows share a parameter key with a longer name holding \"4 4 methylenedi phenyl isocyanate\" but are printed under names without these words (that key is wider than the name), or keyed to a CAS number \"4 4 methylenedi phenyl isocyanate\" does not name (another substance, whatever words its name holds): not sent. Ask for one by its name or CAS number."}},"total":4,"offset":0,"returned":4,"next_offset":null,"rows":[{"id":"12858a91175fa82a","parameter":"Methylene diphenyl diisocyanate","value":"400","value_num":400,"unit":"mg/kg","direction":"max","kind":"threshold","medium":"soil","level":"regional","parameter_key":"cas:101-68-8","place":["US-FL"],"conditions":["residential direct exposure (Table II, Direct Exposure - Residential column)","Note: If more than one contaminant is present at a site, the direct exposure values are to be modified, if necessary, such that the sum of the hazard quotients for non-carcinogenic contaminants affecting the same organ(s) is 1 or less. For carcinogens, the direct exposure values shall be modified such that the cumulative lifetime risk level posed by the contaminants is 1.0E-06, as presented in Appendix D 'Draft Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 62-777, F.A.C.', dated February 2005."],"cite":{"instrument":"us_fl_62_777","title":"Chapter 62-777, F.A.C. (Florida): cleanup target levels — Table I Groundwater and Surface Water, Table II Soil","issuer":"State of Florida, Department of Environmental Protection (Division of Waste Management)","edition":"Chapter 62-777, F.A.C., Tables I and II as the Department of Environmental Protection posts them as spreadsheets: Table I '62-777-TechRprt-Table1-Groundwater-CTLs_Feb2005 .xlsx' and Table II '62-777TechReportApril2005Table2SoilCTLs-CAS_24Oct13_0.xlsx' (server Last-Modified 2025-10-30 for both), fetched 2026-10-15; DEP's petroleum excerpt of the same tables (held) dates them 'effective April 17, 2005'","source_url":"https://floridadep.gov/sites/default/files/62-777-TechRprt-Table1-Groundwater-CTLs_Feb2005%20.xlsx","source_sha256":"d4eff83970269c22f672f6723b5d139b992eccbb64afc372622abb56f23d91c9","fetched_at":"2026-10-15","source_status":{"checked":"2026-10-15","status":"not verified"},"section":"Ch. 62-777 F.A.C. Table II, Soil Cleanup Target Levels, Direct Exposure - Residential (DEP spreadsheet, sheet TTable2, row 332)","page":null,"quote":"row 332: Methylene diphenyl diisocyanate | -Nasal  | 101-68-8 | 400 | 2100 | NA | NA | NA | NA"}},{"id":"32bd1e815433e628","parameter":"Methylene diphenyl diisocyanate","value":"2100","value_num":2100,"unit":"mg/kg","direction":"max","kind":"threshold","medium":"soil","level":"regional","parameter_key":"cas:101-68-8","place":["US-FL"],"conditions":["industrial direct exposure (Table II, Direct Exposure - Industrial column)","Note: If more than one contaminant is present at a site, the direct exposure values are to be modified, if necessary, such that the sum of the hazard quotients for non-carcinogenic contaminants affecting the same organ(s) is 1 or less. For carcinogens, the direct exposure values shall be modified such that the cumulative lifetime risk level posed by the contaminants is 1.0E-06, as presented in Appendix D 'Draft Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 62-777, F.A.C.', dated February 2005."],"cite":{"instrument":"us_fl_62_777","title":"Chapter 62-777, F.A.C. (Florida): cleanup target levels — Table I Groundwater and Surface Water, Table II Soil","issuer":"State of Florida, Department of Environmental Protection (Division of Waste Management)","edition":"Chapter 62-777, F.A.C., Tables I and II as the Department of Environmental Protection posts them as spreadsheets: Table I '62-777-TechRprt-Table1-Groundwater-CTLs_Feb2005 .xlsx' and Table II '62-777TechReportApril2005Table2SoilCTLs-CAS_24Oct13_0.xlsx' (server Last-Modified 2025-10-30 for both), fetched 2026-10-15; DEP's petroleum excerpt of the same tables (held) dates them 'effective April 17, 2005'","source_url":"https://floridadep.gov/sites/default/files/62-777-TechRprt-Table1-Groundwater-CTLs_Feb2005%20.xlsx","source_sha256":"d4eff83970269c22f672f6723b5d139b992eccbb64afc372622abb56f23d91c9","fetched_at":"2026-10-15","source_status":{"checked":"2026-10-15","status":"not verified"},"section":"Ch. 62-777 F.A.C. Table II, Soil Cleanup Target Levels, Direct Exposure - Industrial (DEP spreadsheet, sheet TTable2, row 332)","page":null,"quote":"row 332: Methylene diphenyl diisocyanate | -Nasal  | 101-68-8 | 400 | 2100 | NA | NA | NA | NA"}},{"id":"9bd45a720e2b2e1b","parameter":"Methylenediphenyl Diisocyanate","value":"850000","value_num":850000,"unit":"mg/kg","direction":"max","kind":"guideline","medium":"soil","level":"national","parameter_key":"cas:101-68-8","place":["US"],"conditions":["Resident Soil (mg/kg)"],"cite":{"instrument":"us_rsl_soil","title":"US EPA — Regional Screening Levels (RSLs), Summary Table (TR=1E-06, THQ=1.0), November 2024 — Soil","issuer":"U.S. Environmental Protection Agency (EPA)","edition":"November 2024","source_url":"https://semspub.epa.gov/src/document/HQ/405270","source_sha256":"0160dc81b4f55d738a354a74de92488f149946ebfa7c6a6c64592f45348043d7","fetched_at":"2026-09-19","source_status":{"checked":"2026-10-15","status":"not verified"},"section":null,"page":null,"quote":null,"table":"sols","column":"residentiel"}},{"id":"c54c6d748d96e87f","parameter":"Methylenediphenyl Diisocyanate","value":"3600000","value_num":3600000,"unit":"mg/kg","direction":"max","kind":"guideline","medium":"soil","level":"national","parameter_key":"cas:101-68-8","place":["US"],"conditions":["Industrial Soil (mg/kg)"],"cite":{"instrument":"us_rsl_soil","title":"US EPA — Regional Screening Levels (RSLs), Summary Table (TR=1E-06, THQ=1.0), November 2024 — Soil","issuer":"U.S. Environmental Protection Agency (EPA)","edition":"November 2024","source_url":"https://semspub.epa.gov/src/document/HQ/405270","source_sha256":"0160dc81b4f55d738a354a74de92488f149946ebfa7c6a6c64592f45348043d7","fetched_at":"2026-09-19","source_status":{"checked":"2026-10-15","status":"not verified"},"section":null,"page":null,"quote":null,"table":"sols","column":"industriel"}}],"next":[{"tool":"check_values","says":"Has your user measured this? check_values sets each of their results beside every row held here, with a verdict and the row's cite.","arguments":{"place":"US-FL"},"needs":{"rows":"Your user's measured results, as their table prints them: [{parameter: \"4 4 methylenedi phenyl isocyanate\", value, unit}, ...], any other parameters too."},"post":"/api/v1/check"},{"tool":"read_certificate","says":"Has your user a laboratory certificate? read_certificate reads every row it prints, each with its page, and checks them against these limits.","arguments":{"place":"US-FL"},"needs":{"content_base64":"The laboratory's certificate (PDF) or its XLSX, XLS or CSV export, as base64; or file_url, a public https address of it."},"post":"/api/v1/certificate"}]}